Impact of anode materials on electrochemical degradation of carbamazepine: a case study of producing the main by-product 10,11-Epoxycarbamazepine after electrochemical degradation of Carbamazepine

Zainab, Haider Mussa and Fouad, Fadhil Al-Qaim (2022) Impact of anode materials on electrochemical degradation of carbamazepine: a case study of producing the main by-product 10,11-Epoxycarbamazepine after electrochemical degradation of Carbamazepine. Indonesian Journal of Chemistry (Indones. J. Chem), 22 (4): 5. pp. 929-943. ISSN 1411-9420 e_ISSN: 2460-1578

[thumbnail of Jurnal_Zainab Haider Mussa_University of Al-Ameed Iraq_2022.pdf]
Preview
Text
Jurnal_Zainab Haider Mussa_University of Al-Ameed Iraq_2022.pdf - Published Version
Available under License Creative Commons Attribution Non-commercial No Derivatives.

Download (1MB) | Preview

Abstract

Copper (Cu), nickel (Ni), platinum (Pt), and graphite (G)” have been applied to the electrochemical degradation of carbamazepine (CBZ) from its aqueous solution. The optimum results were observed with graphite anode as follows: fully complete removal of CBZ, 0.0758 min−1 rates constant, and 0.59 Wh/mg consumption energy under these conditions: 5 V, 0.5 g NaCl, and a graphite anode. Kinetics was also considered in the present study, in which rate constants ranged between 0.0023 and 0.0886 min−1. It was observed that applied voltage has an effect on consumption energy giving 0.34, 0.59, and 1.08 Wh/mg using 3, 5, and 7 V, respectively. Field emission scanning electron microscope (FESEM) and energy dispersive X-ray spectroscope (EDS) were used to characterize the organo-metallic precipitates which were formed using Ni and Cu anodes. The main by-product of 10,11-epoxycarbamazepine (EPX-CBZ) was elucidated and monitored using liquid chromatography-time of flight/mass spectrometry (LC-ToF/MS). Therefore, graphite is suggested to be a promising electrode in which it is exhibited good performance compared to other electrodes in terms of removal and consumption of energy.

Item Type: Article
Uncontrolled Keywords: Electrochemical degradation, Carbamazepine, 10,11-epoxycarbamazepine, Anode materials, Graphite anode
Subjects: Chemistry > Industrial Chemistry & Chemical Process Engineering
Depositing User: Djaenudin djae Mohamad
Date Deposited: 11 May 2023 06:31
Last Modified: 11 May 2023 06:31
URI: https://karya.brin.go.id/id/eprint/16457

Actions (login required)

View Item
View Item