Mempelajari pengaruh laser terhadap senyawa - senyawa kompleks Zr - nitrat - TBP

Result of observation of laser N2 radiation effect wich have maximum intencitiy at 337,1 nm on zicronium compleks compound was presented. Observation of absorption spectra from the irradiation result show the increase in abasorption of the solution of Zn - nitrate complexes at 298 nm and the decrease in absorption of the solution Zr - nitrate - TBP complexes at 270 nm. Therefore it can be concluded that laser irradiation has decomposed the complexes. Decomposition reaction of the Zr - nitrate was a zero order reaction with k= -0,307.10-4 M/days and decomposition reaction of the Zr - nitrate - TBP was a 2nd order reaction with k= 4975,6 m-1.hours-1.