Structural and Phase Transition Changes of Sodium Dodecyl Sulfate Micellar Solution in Alcohols Probed by Small-Angle Neutron Scattering (SANS)

Abstract. Small-angle neutron scattering (SANS) measurements on 0.3M sodium dodecyl sulfate (SDS) micellar solutions
have been performed in the presence of n-alcohols, from ethanol to decanol at different alcohol concentrations, 2-
10 wt%. The ellipsoid micellar structure which occurred in the 0.3M SDS in aqueous solution with the size range of 30-
50 Å has different behavior at various hydrocarbon chain length and concentration of alcohols. At low concentration and
short chain-length of alcohols, such as ethanol, propanol, and butanol, the size of micelles reduced and had a sphericallike
structure. The opposite effect occurred as medium to long chain alcohols, such as hexanol, octanol and decanol was
added into the 0.3M SDS micellar solutions. The micelles structure changed to be more elongated in major axis and then
crossed the critical phase transition from micellar solution into liquid crystal phase as lamellar structure emerged by
further addition of alcohols. The inter-lamellar distances were also depending on the hydrocarbon chain length and
concentration of alcohols. In the meantime, the persistent micellar structures occurred in addition of medium chain of nalcohol,
pentanol at all concentrations.
Keywords: small-angle neutron scattering, micellar solution, micelles, liquid crystals, lamellar structure.
PACS: 61.05.fg; 61.30.-v; 64.70.M-; 64.70.pv.